Key words: Mill scale, Reduction by hydrogen. 1. Introduction In several iron and steel making processes, about 500 kg/ton of solid wastes of different nature are generated. One of this wastes is the mill scale which represents about 2% of steel produced [1]). Mill scale is very attractive industrial waste due to very rich in iron
Get PriceLower mill scale size (300 m) particles, higher reduction temperature (1100 C), higher reduction time (240 mins), and mill scale to coal ratio (1:3) yielded higher percentage of metallic iron
This paper presents an initial part of a project devoted to the recycling of mill scale in the form of self-reducing briquettes. First chemical and morphological characteristics of mill scale were investigated and next its gaseous reduction behavior was studied by thermogravimetry. The chemical characterization showed that wustite is the major constituent of this waste matter, with small
Jan 01, 2021 Reduction of mill scale has proven to be one of the best techniques and processes to extract iron from this waste cum byproduct of steel making industry. Sponge iron or iron powder is extracted from the mill scale by making use of direct reduction process which in the presence of desirable reducing agents
Feb 11, 2020 The reduction study of the mill scale pellets has been carried out using the statistical design of experimental approach employing the response surface methodology. Under optimum conditions such as a temperature of 1246 C, a time of 1.52 h, and coal-to-mill scale ratio of 0.58, around 88–89% metallization is obtained
The mill scale is a waste from the iron and steel industry. Due to the high content of iron in the form of oxides, it is an attractive material for the recovery of metallic iron by reduction. The product of mill scale reduction is an iron with a very extended surface and a high affinity for oxygen. The smaller iron particles are, the easier it is for spontaneous rapid oxidation, which can be
Aug 08, 2014 Mill scale is a very attractive industrial waste due to its promising scope in many applications. Recovery of iron powder from iron oxide in mill scale could be considered as a method of beneficiation. The reduction of ground and powdered mill scale from rolling mill was studied using hydrogen gas as the reducing agent. The mill scale was subjected to low and high energy milling in
This conveys the difficulty in reduction of mill scale using regular reduction agents like, coal, coke, graphite, CO gas, etc. Literature reported discloses that, reduction of mill scale with carbonaceous solid or gaseous reducing agents, produces iron powder with maximum of 85.5% Fe (Met)6,10,15) while further annealing in hydrogen improves
reduction of rolling mill scale M. I. Martı n* 1,2 ,F.A.Lopez 3 and J. M. Torralba 4 Rolling mill scale is a solid byproduct of the steelmaking industry that contains metallic iron and
In the fundamental studies a mill scale was rarely used as an iron oxides bearing component of self-reducing mixture. Therefore, in the first paper,1) the chemical and morpho-logical characteristics of the mill scale were investigated together with its reduction behaviors. The chemical and structural characterization of the mill scale showed that
Mill scale is very attractive industrial waste due to its richness in iron (about = 72% Fe). In this paper, the characterizations of mill scale were studied by different methods of analyses. The produced mill scale briquettes were reduced with hydrogen at varying temperatures, and the reduction kinetics was determined. Two models were applied and the energy of activation was calculated
Abstract Rolling mill scale is a solid byproduct of the steelmaking industry that contains metallic iron and three types of iron oxides: w stite, haematite and magnetite. It also contains traces of non-ferrous metals, alkaline compounds and oils from the rolling process. A study was made of the reduction of mill scale to sponge iron using coke at different temperatures and times
Jan 22, 2021 1: Identifying the effect on mill scale reduction due to the addition of limestone with coal, and determining the optimum amount of limestone which should be mixed with coal to obtain the maximum reduction value of mill scale. 2: Calculating the kinetics of mill scale reduction for non-addition and addition of limestone. 3
This study develops a fast and simple way to produce high purity magnetite (Fe3O4) microparticles from mill scale by using hydrogen reduction with the addition of vapour as a retarding agent. By optimising the reduction temperature and gas flow rate, the characterisations by X-ray diffractometry technique shown that the Fe3O4 fraction of over 93 wt.-% is shown at the reduction temperature of
In this work, a mixture of mill scale with 5 wt% molasses as binder was pressed under pressure of 200 MPa to prepare briquettes. The reduction process was performed at the temperature of 1000, 1050, 1100, 1150 and 1200 C in the bed of A3 fine coal as the reductant. The degree of reduction was evalu
Reduction of the mill scale is achieved by heating in a stream of hydrogen or in a stream of dissociated ammonia. The following technological parameters have been determined: hydrogen flow rate
Jan 01, 2021 Fig. 11 depicts the % of metallic iron powder formed in response to the mill scale size (300 to 825 ) at a reduction temperature of 1100 C, reduction time 240 min and mill scale to coal ratio considered is 1:3. It was observed that higher degree of metallization was attained for the smaller sized (300 ) mill scale particles 300 , indicating the importance and influence of the particle size
The maximum reduction was found to be 90% in mill scale (15 g) and coal (13.5 g) sample having 45–90 m particle size, 1:1.3 ratio, reduced at 950 C for 150 min
Office Add: Kexue Revenue, High and New Technology Industrial Development Zone, Zhengzhou, China
Email: [email protected]